鞭毛模板制备贵金属纳米颗粒/TiO2复合薄膜及光催化活性研究
Flagella-Templated Process to Noble Metal Nanoparticles/TiO2 Composite Films and Their Photocatalytic Activity
摘要:
通过大肠杆菌鞭毛控制
Au
和
Ag
的纳米颗粒的生长及组装,获得稳定的鞭毛
/
金属纳米颗粒分散液。以此分散液以及透析钛溶胶为原料,通过浸渍提拉法制备
TiO
2
/Au(Ag)/TiO
2
夹心结构的复合薄膜。通过透射电子显微镜
(
TEM
)
、紫外
–
可见分光光度计
(
UV-visible spectroscopy
)
对鞭毛、鞭毛
/
贵金属纳米颗粒进行表征。研究发现,该复合膜的夹心结构起到了稳定金属纳米颗粒的作用,而金属纳米颗粒的引入赋予了该复合膜可见光催化活性。
Abstract:
In this work, flagella are used to control over the growth and assembly of Au and Ag nanoparticles, and a stable dispersion of flagella/metal nanoparticle is successfully obtained. A composite film with a TiO
2
/Au(Ag)/TiO
2
sandwich structure is prepared by means of a dip-coating method where a dialyzed TiO
2
solution and flagella stabilized Au and Ag nanoparticles are used as raw materials. TEM and UV-visible spectroscopy characterizations reveal that the sandwich structures play a role in stabilizing metal nanoparticles in the composite films and visible light photocatalytic activity is attributed to the existence of Au and Ag nanoparticles.
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