鞭毛模板制备贵金属纳米颗粒/TiO2复合薄膜及光催化活性研究
Flagella-Templated Process to Noble Metal Nanoparticles/TiO2 Composite Films and Their Photocatalytic Activity
DOI:10.12677/MS.2013.33023,PDF,HTML,XML,下载: 3,826浏览: 10,081国家自然科学基金支持
作者:王莉霞,翁永根,何涛,徐金光:烟台大学化学化工学院
关键词:微生物模板法TiO2薄膜Ag/TiO2Au/TiO2光催化Microbial Template Method; TiO2 Film; Ag/TiO2; Au/TiO2; Photocatalysis
摘要: 通过大肠杆菌鞭毛控制 Au Ag 的纳米颗粒的生长及组装,获得稳定的鞭毛 / 金属纳米颗粒分散液。以此分散液以及透析钛溶胶为原料,通过浸渍提拉法制备 TiO 2 /Au(Ag)/TiO 2 夹心结构的复合薄膜。通过透射电子显微镜 ( TEM ) 、紫外 可见分光光度计 ( UV-visible spectroscopy ) 对鞭毛、鞭毛 / 贵金属纳米颗粒进行表征。研究发现,该复合膜的夹心结构起到了稳定金属纳米颗粒的作用,而金属纳米颗粒的引入赋予了该复合膜可见光催化活性。
Abstract: In this work, flagella are used to control over the growth and assembly of Au and Ag nanoparticles, and a stable dispersion of flagella/metal nanoparticle is successfully obtained. A composite film with a TiO 2 /Au(Ag)/TiO 2 sandwich structure is prepared by means of a dip-coating method where a dialyzed TiO 2 solution and flagella stabilized Au and Ag nanoparticles are used as raw materials. TEM and UV-visible spectroscopy characterizations reveal that the sandwich structures play a role in stabilizing metal nanoparticles in the composite films and visible light photocatalytic activity is attributed to the existence of Au and Ag nanoparticles.
文章引用:王莉霞, 翁永根, 何涛, 徐金光. 鞭毛模板制备贵金属纳米颗粒/TiO2复合薄膜及光催化活性研究[J]. 材料科学, 2013, 3(3): 121-124. http://dx.doi.org/10.12677/MS.2013.33023

参考文献

[1] D. Zhang, T. Yoshida, T. Oekermann, et al. Room-temperature synthesis of porous nanoparticulate TiO2 films for flexible dye-sensitized solar cells. Advanced Functional Materials, 2006, 16: 1228-1234.
[2] P. Innocenzi, L. Malfatti and G. J. A. A. Soler-Illia. Hierarchical mesoporous films: From self-assembly to porosity with different length scales. Chemistry of Materials, 2011, 23: 2501-2509.
[3] S. S. Soni, M. J. Henderson, J.-F. Bardeau, et al. Visible-light photocatalysis in titania-based mesoporous thin films. Advanced Materials, 2008, 20: 1493-1498.
[4] W. Hou, S. B. Cronin. A review of surface plasmon resonance-enhanced photocatalysis. Advanced Functional Materials, 2012, 23(13): 1612-1619.
[5] L. D. Rogatis, M. Cargnello, V. Gombac, et al. Embedded phases: A way to active and stable catalysts. Chem SusChem, 2010, 3(1): 24-42.
[6] M. T. Kumara, B. C. Tripp and S. Muralidharan. Self-assembly of metal nanoparticles and nanotubes on bioengineered flagella scaffolds. Chemistry of Materials, 2007, 19(8): 2056-2064.
[7] 沈萍. 微生物学[M]. 北京: 高等教育出版社, 2000: 59-60.

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